Kuchiki Rukia. The first Death God who Ichigo had met and then became Ichigo's closest companion at heart. After having transferred her powers to Ichigo, she remained in a gigai as a normal human. She was the one who taught Ichigo many things about Soul Society and the Death God customs, while on the other hand, learnt many interesting human traits while in her body form in the mortal world. She is the only one who understands Ichigo the most, and proves to be a very important support for Ichigo's striving battles and the hardships they face together.
Innoue Orihime. One of Ichigo's classmates who has a very big crush on him, but is afraid to act on it. She lost her brother in a car accident many years ago, and he came back as a hollow to eat her soul. After being in contact with Ichigo's shinigami form, her spiritual power was awakened. Innoue's powers involves the use of pixies to form protective shields and healing powers that rejuvenates the dying back to their original state. She also has an offensive ability which can slice opponents at dire speed. Her abilities give her the confidence to travel with Ichigo through the dangers in Soul Society. 
Sado Yasutora. Also nicknamed as "Chad". He is as young as Ichigo but has a huge hulk looking body. Before his spiritual powers were tapped, Sado seems to be incredibly strong who does not seem to get easily injured even after being knocked by a vehicle. The threat of Hollows awakened Sado's powers of having a weird-looking right arm which is capable of dishing out overwhelming blows. Seeing that his right arm holds such power, Sado uses it to battle alongside Ichigo against the onslaught of the Hollows.
Ishida Uryuu. He belongs to a group known as the Quincy. The Quincy's objective is in a way similiar to Death Gods, seeking Hollows and purging them from the human world. The only difference is that while Death Gods purify Hollows so that the Hollow will return to Soul Society as a normal soul, the Quincy destroys the Hollows completely. Such will cause the upset in the balance of souls in Soul Society and the human world. Due to this fact, a conflict arose in the past and the Quincy were wiped out. Ishida, being the last Quincy, had to abandon his old grudges against the Death Gods if he were to save the world from Hollows.
Urahara Kisuke. This is the manager of the Uraha shop, who has an unshaven face and wears a beach hat most of the time. He cares alot about the reputation of the shop and tries his best to provide his costomers with the products that they want. When he realizes the mistake he made in giving Rukia a mod soul, he descides he will fix the problem himself. When Ichigo lost his 'borrowed' Death God powers from Rukia, Urahara seems to have shown that he himself possess some sort of Death God powers, but that will remain as a mystery till the later parts.
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